Skip to main content

Advertisement

Table 1 Product ion of cocoa pod extract in negative mode

From: Phenolic composition, antioxidant, anti-wrinkles and tyrosinase inhibitory activities of cocoa pod extract

Class Compound Retention time, t R (min) m/z Reference in PBE
Sugar Gluconic acid sodium salt/glucose acid 0.787 195,177,129,85,75 34,35 Yes
Carboxylic acid Tartaric acid 1.184 149,105,87,73 34 No
Flavonoid/flavonol Rhamnetin 1.315 315,241,139,108,97,80,70 34 No
Carboxylic acid Citric acid 1.447 191,111,87 53,35 Yes
Phenolic acid Protocatechuic acid 1.842 153,109,65 38,39 Yes
Phenolic acid Protocathecuic derivatives/nucleotide 1.972 329,241,199,108,97,69 41/35 No
Phenolic acid Protocathecuic derivatives/nucleotide 1.974 329,241,139,97,80 41/35 No
  Unknown   2.106 330,241,122,96,80 - No
Phenolic acid p-hydroxybenzoic acid 2.238 137,93 36,40 Yes
Phenolic acid Salicyclic acid 2.238 137,108,91,65 35 Yes
  Unknown   2.500 363,241,122,96,59 - No
Phenolic acid Methyl salicylate 2.633 151,139,124,91,65 35 No
Nucleotide disodium salt, nucleotide 2.763 401,327,69 35 No
Phospholipid Phospholipid derivatives 2.897 381,249,161,113,98,85,68 35 No
Glucosinolate Glucosinolate derivatives 3.029 379,155,59 35 No
Flavonoid Sineginhomoorientin derivatives 3.161 355,225,207,96,69,59 35,42 No
  Unknown   3.292 358,245,222,178,161,135,123 - No
  Unknown   3.293 358,222,178,161,151,135,123 - Yes
  Unknown   3.423 452,408,372,328,285,250,230,190,178,160,148,135 - No
Flavones-Sugar Apigenin-c-glucose-c-pentoside 3.425 563,545,473,443,395,383,365,353,325,311,297,233 43 No
  Unknown   3.557 357,241,139,96 - No
Glucosinolate Glucosinolate derivatives 3.688 372.2,285.1,136,178,147,160.2,135 35 No
Glucosinolate Glucosinolate derivatives 3.822 439.2,314,300.1,269.1,180.1,151.1,96.9,80.1 35,42 No
Glucosinolate Glucosinolate derivatives 4.086 371,281,241,151,96 35 No
Terpenoid Terpenoid derivatives 4.351 345,201,171,155,59 35 No
Flavonoid/Flavonol Kaempferol derivatives 4.879 723,677,659,550,451,367,225 34 Yes
Terpenoid Terpenoid derivatives 5.010 345,99,59 35 No
Flavonoid Flavone derivatives 5.143 327,309,197 35 No
  Unknown   5.404 329,229,211,171,139,99 - No
Flavone Flavone/luteolin 5.407 329,311,229,211,171,139,127,99,69 44 No
Flavonoid Flavone derivatives 5.535 327,205,183,171,69,59 35 No
Ketone-Sugar Ribulose1,5-bisphosphate 5.667 309,265,209,193,151,137,109 53 No
Terpenoid Crysoplenol 5.802 330,172 35 No
Flavonoid Flavones derivatives 6.199 305,287,249,163,135,93 37,54,45,46 No
Flavones-Sugar apigenin glycoside 6.594 313,295,183,171,129,99,58 34,44 No
Phenylpropanoid Chlorogenic acid derivatives 6.858 353,97,80 34 No
  Unknown   7.377 339,239,183,170,99 - Yes
Flavonoid Flavones derivatives 7.384 295,277,181,171 35 No
Flavonoid Flavones derivatives 7.516 293,249,195,113 35 No
Flavonoid Flavones derivatives 7.516 293,249,236,220,205,190,177,164,148,81 35 No
Carboxylic acid Malic acid 8.042 133, 115,71 34,47,48,49,53,35 Yes
Stillbenoids Resveratrol 8.567 277 50 No
Stillbenoids Resveratrol 8.567 227 37,51 No
Fatty acid Linoleic acid 9.094 279 41 No
Vitamin Flavin mononucleotide 9.218 455 43 No
Fatty acid Oleic acid 9.620 281 41 No
Flavonoid/flavone Linarin/acacetin 14.350 283 52 Yes