Table 4 1 H-NMR and 13 C-NMR data of compound 1 and 2 compared to literature
1H (600 MHz) | 1Hlit | 13C (600 MHz) | 13Clit | ||||
|---|---|---|---|---|---|---|---|
CPD 1 | CPD 2 | CPD 1 | CPD 1 | CPD 2 | CPD 1 [24] | CPD 2 [24] | |
1 | 0.88(1H,t) | 0.64(1H,s) 1.21(1H,t) | 0.98(m) | 39.4(t) | 38.0 | 39.9 | 38.8 |
1.24(1H,t) | |||||||
2 | 1.98(2H,m) | 1.05(1H.m) | 34.4(t) | 27.4 | 34.1 | 27.2 | |
3 | - | 4.26(1H,m) | 1.83(1Hm) | 217.2(s) | 74.3 | 218.3 | 78.9 |
1.96(1Hm) | |||||||
4 | - | 47.8(d) | 38.7 | 47.2 | 38.9 | ||
5 | 0.68(t) | 54.5(d) | 56.5 | 54.5 | 55.3 | ||
6 | 1.40(m) | 19.8(t) | 18.4 | 19.8 | 18.3 | ||
1.6(m) | |||||||
7 | 1.35(m) | 34.2 | 36.9 | 34.3 | |||
1.41(m) | |||||||
8 | - | 43.1(s) | 39.8 | 42.4 | 40.9 | ||
9 | 1.68(m) | 49.6 | 50.1 | 50.3 | 50.4 | ||
10 | - | 37.9 | 37.1 | 37.2 | |||
11 | 1.26(m) | 21.4 | 22.5 | 21.5 | 20.9 | ||
1.42(m) | |||||||
12 | 1.41(m) | 26.2 | 25.8 | 25.2 | 25.3 | ||
1.52(m) | |||||||
13 | 0.69(m) | 37.6 | 33.3 | 37.0 | 37.3 | ||
14 | - | 47.0 | 44.1 | 47.8 | 42.7 | ||
15 | 1.41(m) | 63.3 | 26.4 | 69.0 | 27.0 | ||
1.52(m) | |||||||
16 | 1.33(m) | 28.5 | 40.3 | 29.2 | |||
1.42(m) | |||||||
17 | - | 48.6 | 47.9 | 47.8 | |||
18 | 1.77(dd) | 50.9 | 48.8 | 48.8 | |||
19 | 3.01(dt) | 48.4 | 47.2 | 47.8 | |||
20 | - | 155.5 | 150.5 | 149.9 | 150.6 | ||
21 | 1.41(m) | 29.0 | 30.0 | 29.8 | |||
1.51(m) | |||||||
22 | 1.35(m) | 33.5 | 31.5 | 33.9 | 34.0 | ||
1.41(m) | |||||||
23 | 0.84(3H,s) | 0.85(3H,s) | 0.81(s) | 26.9 | 27.5 | 26.6 | 28.0 |
24 | 0.86(3H,s) | 0.86(3H,s) | 0.83(s) | 21.4 | 16.2 | 21.0 | 15.4 |
25 | 0.94(3H,s) | 0.90(3H,s) | 0.93(s) | 14.1 | 18.2 | 16.1 | 16.1 |
26 | 0.99(3H,) | 0.97(3H,s) | 0.99(s) | 16.2 | 16.3 | 16.3 | 16.0 |
27 | 0.78(3H,s) | 0.76(3H,s) | 1.02(s) | 5.5 | 16.1 | 8.1 | 14.8 |
28 | 3.8(1H,s,OH) | 3.58 (1H, s,OH) | 62.5 | 63.0 | 61.5 | 60.2 | |
29 | 4.8(1H,d) 4.7(1H,s) | 4.85(1,m) 4.72-4.75 (1,m) | 4.74(brs) 4.65(br,s) | 106.1(t) | 106.0 | 110.0 | 109.6 |
30 | 1.64 (s) | 1.63(s) | 1.69(s) | 18.1(q) | 20.9 | 19.1 | 19.1 |